MALLINCKRODT INC.,SCIENCE PRODUCT DIVISION -- AMYL ACETATE -- 6810-00-924-5220
===================== Product Identification ===================== Product ID:AMYL ACETATE MSDS Date:04/06/1989 FSC:6810 NIIN:00-924-5220 === Responsible Party === Company Name:MALLINCKRODT INC.,SCIENCE PRODUCT DIVISION Address:PARIS BYPASS Box:M City:PARIS State:KY ZIP:40361 Country:US Info Phone Num:314-982-5000 Emergency Phone Num:(314)982-5000 CAGE:62910 === Contractor Identification === Company Name:MALLINCKRODT SPECIALTY CHEMICALS CO Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:908-859-2151 CAGE:62910 ============= Composition/Information on Ingredients ============= Ingred Name:N-AMYL ACETATE (SARA III) CAS:628-63-7 RTECS #:AJ1925000 Fraction by Wt: >95.0% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 6,500 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE-INHALE:MAY CAUSE RESPIRATORY TRACT IRRITATION,NARCOSIS,HEADACHE,FATIGUE,COUGH,NAUSEA,DIZZINESS,CNS DEPRESSION, KIDNEY & LIVER DAMAGE & EDEMA OF THE GLOTTIS.ORAL:MAY BE ABSORBED CAUSING SYMPTOMS SIMILAR TO INHALATION.EYES/SKIN:MAY CAUSE IRRITATION,REDNESS & PAIN.LIQUID DEGREASES THE SKIN.CHRONIC-DERMATITIS Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:MAY CAUSE RESPIRATORY TRACT IRRITATION, NARCOSIS, HEADACHE, FATIGUE, COUGH, NAUSEA, DIZZINESS, CNS DEPRESSION, KIDNEY & LIVER DAMAGE & EDEMA OF THE GLOTTIS. ORALLY MAY BE ABSORBED CAUSING SYMPTOMS SIM ILAR TO INHALATION. MAY CAUSE EYES AND SKIN IRRITATION, REDNESS & PAIN. LIQUID DEGREASES THE SKIN. Medical Cond Aggravated by Exposure:USE OF ALCOHOLIC BEVERAGES MAY ENHANCE TOXIC EFFECTS. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IMMEDIATELY.EYE/SKIN: FLUSH WITH WATER FOR AT LEAST 15 MINUTES.HOLD EYELIDS OPEN.INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.ORAL:IF CONSCIOUS,DRINK WATER & INDUCE VOMITING.CALL A PHYSICIAN IMMEDIATELY.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:60.0F,15.6C Autoignition Temp:Autoignition Temp Text:680F Lower Limits:1.1 Upper Limits:7.5 Extinguishing Media:CO2, FOAM/DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS AWAY. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH- APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:ABOVE FLASH POINT, VAPOR-AIR MIXTURES ARE EXPLOSIVE WITHIN FLAMMABLE LIMITS. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION SOURCE AND FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE & EVAC AREA.USE PROTCTV CLOTHG & RESP PROTCTION FM VAP.CONTAIN & RECOVR LIQ WHEN POSS.SPILLS MAY BE ABSORBD W/INERT MATL,VERMICULITE,DRY SAND & PLACE IN A CONTNR PENDING DISPOSAL.DO NOT FLUS H TO SEWER.HAVE DRY POWDER EXTINGUISHERON HAND. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORAGE-KEEP IN TIGHTLY CLOSED CONTAINERS AT COOL,VENTILATED AREA AWAY FROM INCOMPATIBLES.OUTSIDE OR DETACHED STORAGE IS PREFERRED. Other Precautions:AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. KEEP OUT OF SURFACE WATERS AND SEWERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF THE TLV IS EXCEEDED, A NIOSH-APPROVED FULL FACEPIECE CHEMICAL CARTRIDGE RESPIRATOR MAY BE USED. ALTERNATIVELY, A SUPPLIED AIR FULL FACEPIECE RESPIRATOR OR AIRLINED HOOD MAY BE WORN. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:RUBBER OR NEOPRENE Eye Protection:CHEMICAL SAFETY GOGGLES/FULL FACE SHIELD Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND IMPERVIOUS CLOTHING Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health NONE SPECIFIED BY MANUFACTURER. ================== Physical/Chemical Properties ================== HCC:F3 Boiling Pt:B.P. Text:284F,140C Melt/Freeze Pt:M.P/F.P Text:<-148F,<-10 Vapor Pres:4 @ 68F Vapor Density:4.5 Spec Gravity:0.87 Evaporation Rate & Reference:0.42 (N-BUTYL ACETATE=1) Solubility in Water:0.2 G% @ 20C Appearance and Odor:CLEAR COLORLESS LIQUID, CHARACTERISTIC FRUITY ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS, ACIDS AND ALKALIES. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE MAY BE FORMED. ==================== Disposal Considerations ==================== Waste Disposal Methods:COLLECTED SPILLS MAY BE ATOMIZED IN A RCRA- APPROVED COMBUSTION CHAMBER OR SHIPPED TO RCRA APPROVED FACILITY FOR DISPOSAL;RQ(CWA/CERCLA):5000LBS;ENSURE COMPLIANCE W/LOCAL,STATE & FEDERAL REGULATIONS. 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