MACCO ADHESIVES -- AHE90306TNO LN903, LIQUID NAILS ADHESIVE, -- -
===================== Product Identification ===================== Product ID:AHE90306TNO LN903, LIQUID NAILS ADHESIVE, MSDS Date:10/04/1999 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:MACCO ADHESIVES Address:925 EUCLID AVENUE City:CLEVELAND State:OH ZIP:44115 Country:US Info Phone Num:1-800-545-2643 Emergency Phone Num:1-800-545-2643 Resp. Party Other MSDS Num.:AHE 90306TNO CAGE:UO049 === Contractor Identification === Company Name:MACCO ADHESIVES Address:925 EUCLID AVENUE Box:City:CLEVELAND State:OH ZIP:44115 Country:US Phone:1-800-545-2643 CAGE:UO049 ============= Composition/Information on Ingredients ============= Ingred Name:LIMESTONE CAS:1317-65-3 RTECS #:EV9580000 Minumum % Wt:40. Maxumum % Wt:50. OSHA PEL:5 MG/M3 TWA ACGIH TLV:10 MG/M3 TWA Ingred Name:KAOLIN CAS:1332-58-7 RTECS #:GF1670500 Minumum % Wt:10. Maxumum % Wt:20. OSHA PEL:5 MG/M3 TWA ACGIH TLV:2 MG/M3 TWA Ingred Name:QUARTZ CAS:14808-60-7 RTECS #:VV7330000 Minumum % Wt:.1 Maxumum % Wt:1. OSHA PEL:0.1 MG/KG TWA ACGIH TLV:0.1 MG/M3 TWA Ingred Name:BENZENE, 1,3-DIETHENYL-, PLOYMER WITH 1,3-BUTADIENE AND ETHENYLBENZENE. (STYRENE-BUTADIENE POLYMER) CAS:26471-45-4 Minumum % Wt:1. Maxumum % Wt:5. Ingred Name:MAGNESIUM CARBONATE CAS:546-93-0 RTECS #:OM2470000 Minumum % Wt:1. Maxumum % Wt:5. OSHA PEL:5 MG/M3 TWA ACGIH TLV:10 MG/M3 TWA Ingred Name:MINERAL OIL, HEAVY NAPHTHENIC DISTILLATE. (PETROLEUM HYDROCARBON) CAS:64742-52-5 RTECS #:PY8035000 Minumum % Wt:1. Maxumum % Wt:5. OSHA PEL:5 MG/M3 TWA ACGIH TLV:5 MG/M3 TWA ACGIH STEL:10 MG/M3 Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC. (LIGHT ALIPHATC SOLVENT NAPHTHA (PETROLEUM)) CAS:64742-89-8 Minumum % Wt:10. Maxumum % Wt:20. OSHA PEL:300 PPM TWA Ingred Name:2-PROPANONE. (ACETONE) CAS:67-64-1 RTECS #:AL3150000 Minumum % Wt:1. Maxumum % Wt:5. OSHA PEL:1000 PPM ACGIH TLV:500 PPM TWA ACGIH STEL:750 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:DISTILLATES (PETROLEUM), STEAM-CRACKED, POLYMERS WITH LIGHT STEAM-CRACKED PETROLEUM NAPHTHA. (AROMATIC HYDROCARBON RESIN) CAS:68410-16-2 Minumum % Wt:10. Maxumum % Wt:20. Ingred Name:RESIN ACIDS AND ROSIN ACIDS, ESTERS WITH GLYCEROL. (ROSIN GLYCEROL ESTER) CAS:8050-31-5 Minumum % Wt:1. Maxumum % Wt:5. ACGIH TLV:5 MG/M3 TWA ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:INHALATION: PROLONGED INHALATION MAY LEAD TO MUCOUS MEMBRANE IRRITATION, FATIGUE, DROWSINESS, DIZZINESS, AND/OR LIGHTHEADNESS, HEADACHE, UNCOORDINATION, NAUSEA, VOMITING, ABDOMINAL PAIN, COUGHING, DIF FICULTY WITH SPEECH, CENTRAL NERVOUS SYSTEM DEPRESSION, ANESTHETIC EFFECT OR NARCOSIS, DIFFICULTY OF BREATHING, BLOOD ABNORMALITIES, LIVER DAMAGE, KIDNEY DAMAGE, LOSS OF CONSCIOUSNESS, ASPHYXIATION, DEATH. SKIN: IRRITATION. PROLONGED OR REPEATED CONTACT CAN CAUSE DERMATITIS, DEFATTING. EYE: IRRITATION. PROLONGED OR REPEATED CONTACT CAN CAUSE CONJUNCTIVITIS, BLURRED VISION, TEARING OF EYES, REDN ESS (SIGNS & SYMPTOMS OF OVEREXPOSURE) Explanation of Carcinogenicity:QUARTZ (CAS 14808-60-7): NTP: YES, IARC: YES 1. PETROLEUM HYDROCARBON (CAS 64742-52-2): IARC: YES 1. CONTAINS CRYSTALLINE SILICA WHICH IS CONSIDERED A HAZARD BY INHALATION. IARC HAS CLASSIFIED CRYSTA LLINE SILICA AS CARCINOGENIC TO HUMANS (GROUP 1). NTP HAS CLASSIFIED CRYSTALLINE SILICA A REASONABLY ANTICIPATED CARCINOGEN. (SIGNS & SYMPTOMS OF OVEREXPOSURE) Effects of Overexposure:N/P. HEALTH HAZARDS ACUTE AND CHRONIC (CONT): OF EYES, SEVERE EYE IRRITATION. INGESTION MAY CAUSE LUNG INFLAMMATION & DAMAGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS, MUCOUS MEMBRANE IRRITATION, NAUSEA, VOMITING, DIARRHEA, GASTRO-INTESTINAL DISTURBANCES, ABDOMINAL PAIN, CENTRAL NERVOUS SYSTEM DEPRESSION. EXPLANATION OF CARCINOGENICITY (CONT): CRYSTALLINE SILICA IS ALSO A KNOWN CAUSE OF SILICOSIS, A NONCANCEROUS LUNG DISEASE. Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS, LUNG DISORDERS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL HELP FOR ANY BREATHING DIFFICULTY. REMOVE TO FRESH AIR IF INHALATION CAUSES EYE WATERING, HEADACHES, DIZZINESS, OR OTHER DISCOMFORT. GET MEDICAL ATTENTION IF DISCOMFORT OR IRRITATION PERSISTS. SKIN CONTACT: FLUSH FROM SKIN WITH WATER. THEN WASH THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE RE-USE. IF IRRITATION OCCURS, CONSULT A PHYSICIAN. EYE CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER, (OTHER INFORMATION) ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:=-4.4C, 24.F Lower Limits:1.2% Upper Limits:7.0% Extinguishing Media:DRY CHEMICAL OR FOAM, WATER FOG, CARBON DIOXIDE. Fire Fighting Procedures:WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS. FIREFIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE PROTECTION, AND (NIOSH APPROVED - ) SELF-CONTAINED BREATHING APPARATUS. UNUSU AL FIRE & EXPLOSION HAZARD (CONT): UNDER FIRE CONDITIONS EMITTING IRRITANT AND/OR TOXIC GASES. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT OR FIRE. VAPORS MAY IGNITE EXPLOSIVELY AT AMBIENT TEMPERATURES. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL LONG DISTANCES TO A SOURCE OF IGNI TION AND FLASH BACK. CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME HEAT OR FIRE. MAY DECOMPOSE (FIREFIGHTING PROC) ================== Accidental Release Measures ================== Spill Release Procedures:COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA WITH EXPLOSION-PROOF EQUIPMENT. SPILLS MAY BE COLLECTED WITH ABSORBENT MATERIALS. USE NON-SPARKING TOOLS. EVACUATE ALL UNNECESSARY PERSONNEL. PLACE COLLECTED MATERIAL IN PROPER CONTAINER. COMPLETE PERSONAL PROTECTIVE EQUIPMENT MUST BE USED DURING CLEANUP. (OTHER INFORMATION) ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE BELOW 80F. KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. OTHER PRECAUTIONS (CONT): TRANSFERRING TO PREVENT ACCUMULATION OF STATIC CHARGE. WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY BEFOR E EATING OR SMOKING. Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN AND EYES, AND BREATHING OF VAPORS. KEEP CONTAINERS TIGHTLY CLOSED AND UPRIGHT WHEN NO T IN USE. EMPTY CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES. GROUND EQUIPMENT WHEN (HANDLING AND STORA GE PRECAUTIONS) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE EXPOSURE STANDARDS WHEN USING THIS MATERIAL. WHEN RESPIRATORY PROTECTION IS DETERMINED TO BE NECESSARY , USE A NIOSH (CANADIAN Z94.4) APPROVED ELA STOMERIC SEALING-SURFACE FACEPIECE RESPIRATOR OUTFITTED WITH ORGANIC VAPOR CARTRIDGES AND PAINT SPRAY (DUST/MIST) PREFILTERS. (SUPPLEMENTAL SAFETY AND HEALTH) Ventilation:PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP OF VAPORS. USE EXPLOSION-PROOF EQUIPMENT. USE NON-SPARKING EQUIPMENT. Protective Gloves:IMPERVIOUS GLOVES Eye Protection:SAFETY GLASSES OR GOGGLES (ANSI APPROVED - ). Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI CRITERIA . IMPERVIOUS CLOTHING, FACE SHIELD. Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING, SMOKING OR USING TOILET. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health ITEM NAME (CONT): MULTI-PURPOSE CONSTRUCTION ADHESIVE. PRODUCT USE: ADHESIVE / CAULK. RESPIRATORY PROTECTION (CONT): DETERMINE THE PROPER LEVEL OF PROTECTION BY CONDUCTING APPROPRIATE AI R MONITORING. CONSULT 29 CFR 1910.134 FOR SELECTION OF RESPIRATORS (CANADIAN Z94.4). ================== Physical/Chemical Properties ================== Boiling Pt:=56.1C, 133.F Vapor Pres:NOT AVAILABLE Spec Gravity:1.443 pH:NOT AVAILABLE Solubility in Water:NO Appearance and Odor:PASTE, TAN COLOR. ODOR: NOT SPECIFIED BY MANUFACTURER . Percent Volatiles by Volume:32.31 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACIDS, BASES, AMINES, NITRIC ACID Stability Condition to Avoid:ELEVATED TEMPERATURES, CONTACT WITH OXIDIZING AGENT, SPARKS, OPEN FLAME, IGNITION SOURCES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, ACRID FUMES, FORMALDEHYDE, OXIDES OF SULFUR, TOXIC GASES. =================== Toxicological Information =================== Toxicological Information:SUPPLEMENTAL HEALTH INFORMATION: CONTAINS A CHEMICAL THAT MAY BE ABSORBED THROUGH THE SKIN. NOTICE - REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NEERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. OTHER EFFECTS OF OVEREXPOSURE MAY INCLUDE TOXICITY TO THE KIDNEYS . REPRODUCTIVE EFFECTS: NO REPRODUCTIVE EFFECTS ARE ANTICIPATED. MUTAGENICITY: NO MUTAGENIC EFFECTS ARE ANTICIPATED. TERATOGENICITY: NO TERATOGENIC EFFECTS ARE ANTICIPATED. (ECOLOGICAL INFO) ===================== Ecological Information ===================== Ecological:NO ECOLOGICAL TESTING HAS BEEN DONE BY ICI PAINTS ON THIS PRODUCT AS A WHOLE. TOXICOLOGICAL INFO (CONT): LIMESTONE (CAS 1317-65-3): CARCINOGENICITY: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO; LD50: 64 50 MG/KG (ORL, RAT). CLAY (CAS 1332-58-7): CARCINOGENICITY: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO. QUARTZ (CAS 14808-60-7): CARCINOGENICITY: NTP-YES, IARC-YES 1, OSHA-NO, ACGIH-NO. MAGNESIUM CARBONATE (CAS 546-93-0): CARCINOGENICITY: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO; LD50: 16 MG/KG (ITR, MOU). PETROLEUM HYDROCARBON (CAS 64742-52-5): CARCINOGENICITY: NTP-NO, IARC-YES 1, OSHA-NO, ACGIH-NO; LD50: >2000 MG/KG (SKN, RBT).(ECOLOGICAL INFO) ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS. =================== MSDS Transport Information =================== Transport Information:DOT: ADHESIVE,3, UN1133,III. IMDG: ADHESIVE,3, UN1133,III, LIMITED QUANTITY. IATA: NOT AVAILABLE. TDG: NOT AVAILABLE. ECOLOGICAL INFO (CONT): LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM) (C AS 64742-89-8): CARCINOGENICITY: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO; LD50: >3.16 G/KG (SKN, RBT), >5 G/KG (ORL, RAT). ACETONE (CAS 67-64-1): CARCINOGENICITY: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO; LD50: 5800 MG/KG (ORL, RAT), >9400 MG/KG (SKN, GPG). AROMATIC HYDROCARBON RESIN (CAS 68410-16-2): CARCINOGENICITY: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO. ROSIN GLYCEROL ESTER (CAS 8050-31-5): CARCINOGENICIT Y: NTP-NO, IARC-NO, OSHA-NO, ACGIH-NO. ===================== Regulatory Information ===================== SARA Title III Information:ACETONE (CAS 67-64-1): SARA 302 - NO, SARA 313 - NO. Federal Regulatory Information:ACETONE (CAS 67-64-1): CERCLA 302.4 - YES, HAZ AIR POLLUTANT - NO, MARINE POLTNT - NO. AS OF THE DATE OF THIS MSDS, ALL COMPONENTS OF THIS MSDS ARE LISTED (OR ARE EXEMPT FROM LISTING) ON THE TSCA INVENTORY. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR ( CONTROLLED PRODUCT REGULATIONS) AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY CPR. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. 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