DUPONT -- "FREON" 114 -- 6830-00-782-6232 
=====================  Product Identification  =====================

Product ID:"FREON" 114
MSDS Date:01/07/1997
FSC:6830
NIIN:00-782-6232
Status Code:A
=== Responsible Party ===
Company Name:DUPONT
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898-5000
Country:US
Info Phone Num:PROD 800-441-7515 MED: 800-441-3637
Emergency Phone Num:800-441-3637
Chemtrec Ind/Phone:(800)424-9300
CAGE:EO596
=== Contractor Identification ===
Company Name:DDRV STOCK MAINTENANCE DIV/DDRV-H
Address:8000 JEFFERSON-DAVIS HIGHWAY
Box:City:RICHMOND
State:VA
ZIP:23297
Country:US
Phone:804-279-3125
CAGE:02LX8
Company Name:DU PONT E I  DE NEMOURS AND CO INC   PETROCHEMICALS DEPT
Address:1251 BRANDYWINE BLDG
Box:City:WILMINGTON
State:DE
ZIP:19898
Phone:302-773-5676
CAGE:73925
Company Name:DUPONT
Address:1007 MARKET STREET
City:WILMINGTON
State:DE
ZIP:19898-5000
Country:US
Phone:PROD 800-441-7515 MED: 8004413637
CAGE:EO596
Company Name:E I DUPONT DE NEMOURS & CO, FREON PROD (REPLACED BY 73925)
Address:1007 MARKET ST
Box:City:WILMINGTON
State:DE
ZIP:19899
Country:US
Phone:800-441-3637-MED 800-424-9300-TRAN
CAGE:5P414

=============  Composition/Information on Ingredients  =============

Ingred Name:1,2-DICHLORO-1,1,2,2-TETRAFLUOROETHANE ("FREON"114)
CAS:76-14-2
RTECS #:KI1101000
= Wt:100.
OSHA PEL:7000 MG/M3;1000 PPM
ACGIH TLV:6990 MG/M3;1000 PPM
Ozone Depleting Chemical:1

=====================  Hazards Identification  =====================

Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF HIGH CONCENTRATIONS OF
    VAPOR IS HARMFUL & MAY CAUSE HEART IRREGULARITIES, UNCONSCIOUSNESS
    OR DEATH. INTENTIONAL MISUSE OR DELIBERATE INHALATION MAY CAUSE
    DEATH WITHOUT WARNING. VAPOR RED UCES OXYGEN AVAILABLE FOR
    BREATHING & IS HEAVIER THAN AIR. LIQUID CONTACT CAN CAUSE
    FROSTBITE.
Explanation of Carcinogenicity:NONE OF THE COMPONENTS PRESENT IN THIS
    MATERIAL AT CONCENTRATIONS EQUAL TO OR GREATER THAN 0.1 % ARE
    LISTED BY IARC, NTP, OSHA OR ACGIH AS A CARCINOGEN.
Effects of Overexposure:OVEREXPOSURE BY SKIN OR EYE CONTACT MAY INCLUDE
    SKIN IRRITATION WITH DISCOMFORT OR RASH, OR EYE IRRITATION WITH
    DISCOMFORT, TEARING, OR BLURRING OF VISION. CONTACT WITH LIQUID MAY
    CAUSE FROSTBITE. OVE REXPOSURE BY INHALATION OF THE VAPORS MAY
    CAUSE NONSPECIFIC DISCOMFORT SUCH AS NAUSEA, HEADACHE OR WEAKNESS.
    TEMPORARY ALTERATION OF THE HEART'S ELECTRICAL ACTIVITY WITH
    IRREGULAR PAUSE. PALPITATIONS,  OR INADEQUATE CIRCULATION.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING
    DISEASES OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE
    INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.

=======================  First Aid Measures  =======================

First Aid:INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE
    ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
    CALL A PHYSICIAN. SKIN: FLUSH WITH WATER. TREAT FOR FROSTBITE IF
    NECESSARY. GET ME DICAL ATTENTION IF IRRITATION IS PRESENT. EYE:
    IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINS.
    CALL A PHYSICIAN. INGESTION: INGESTION IS NOT CONSIDERED A
    POTENTIAL ROUTE OF EXPOSURE.  NOTE TO PHYSICIAN: BECAUSE OF
    POSSIBLE DISTURBANCES OF CARDIAC RHYTHM, CATECHOLAMINE DRUGS, SUCH
    AS EPINEPHRINE SHOULD BE USED WITH SPECIAL CAUTION IN SITUATIONS OF
    EMERGENCY LIFE SUPPORT.

=====================  Fire Fighting Measures  =====================

Flash Point Method:TOC
Flash Point:WILL NOT BURN
Autoignition Temp:Autoignition Temp Text:N/D
Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA.
Fire Fighting Procedures:SELF CONTAINED BREATHING APPARATUS (SCBA) IS
    REQUIRED IF CYLINDERS RUPTURE OR RELEASE CONTENTS UNDER FIRE
    CONDITIONS. USE WATER SPRAY OR FOG TO COOL CONTAINERS.
Unusual Fire/Explosion Hazard:CYLINDERS ARE EQUIPPED WITH PRESSURE &
    TEMPERATURE RELIEF DEVICES, BUT STILL MAY RUPTURE UNDER FIRE
    CONDITIONS. DECOMPOSITION MAY OCCUR.

==================  Accidental Release Measures  ==================

Spill Release Procedures:VENTILATE AREA, ESPECIALLY LOW PLACES WHERE
    HEAVY VAPORS MIGHT COLLECT. REMOVE OPEN FLAMES. USE SELF CONTAINED
    BREATHING APPARATUS (SCBA) IN CASE OF LARGE SPILLS. COMPLY WITH
    FEDERAL, STATE, & LOCAL R EGULATIONS ON REPORTING RELEASES. REVIEW
    FIRE FIGHTING MEASURES AND HANDLING SECTION BEFORE PROCEEDING WITH
    CLEAN-UP. USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING
    CLEAN-UP.
Neutralizing Agent:NONE PROVIDED BY MFR.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORAGE: CLEAN, DRY AREA. DO NOT HEAT
    ABOVE 125 DEG F. AVOID BREATHING VAPORS & CONTACT OF LIQUID WITH
    SKIN OR EYES. USE WITH SUFFICIENT VENTILATION TO KEEP EMPLOYEE
    EXPOSURE BELOW RECOMMENDED LIMITS.
Other Precautions:NONE PROVIDED BY MFR.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS, NO
    RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT. SELF
    CONTAINED BREATHING APPARATUS (SCBA) IS REQUIRED IF A LARGE RELEASE
    OCCURS.
Ventilation:NORMAL VENTILATION IS GENERALLY ADEQUATE. LOCAL EXHAUST
    SHOULD BE USED FOR LARGE RELEASES. MECHANICAL FOR LOW OR ENCLOSED
    PLACES.
Protective Gloves:IMPERVIOUS GLOVES IF LIQUID CONTECT WITH SKIN IS
    POSSIBLE.
Eye Protection:USE CHEMICAL SPLASH GOGGLES AS NEEDED TO PREVENTLIQUID
    CONTACT WITH THE EYES.
Other Protective Equipment:NONE PROVIDED BY MFR.
Work Hygienic Practices:NONE PROVIDED BY MFR.
Supplemental Safety and Health
EXPOSURE GUIDELINES: EXPOSURE LIMITS FOR "FREON" 114: PEL (OSHA) =
    1,000 PPM, 7,000 MG/M3, 8 HR. TWA. TLV (ACGIH) = 1,000 PPM,  6,990
    MG/M3, 8 HR. TWA, A4.

==================  Physical/Chemical Properties  ==================

HCC:G3
Boiling Pt:=4.C, 39.2F
Decomp Temp:=593.C, 1099.4F
Decomp Text:AUTODECOMPOSITION
Vapor Pres:31 PSIA @ 25 DEG C (77 F)
Vapor Density:6.2(AIR=1)
Spec Gravity:1.46 @77F- LIQUID
Evaporation Rate & Reference:> 1 (CC14 = 1.0)
Solubility in Water:0.013 WT% @ 25 DEG C
Appearance and Odor:LIQUEFIED GAS, CLEAR, COLORLESS, SLIGHT ETHEREAL
    ODOR
Percent Volatiles by Volume:100 WT%

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH ALKALI OR ALKALINE EARTH METALS - POWDERED AL, ZN,
    BE, ETC.
Stability Condition to Avoid:MATERIAL IS STABLE. HOWEVER, AVOID OPEN
    FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:DECOMPOSITION PRODUCTS ARE
    HAZARDOUS."FREON" 114 CAN DECOMPOSE AT HIGH TEMPERATURES (OPEN
    FLAMES, GLOWING METAL SURFACE, ETC.) FORMINGHYDROCHLORIC AND
    HYDROFLUORIC ACIDS, AND POSSIBLY CARBONYL HALIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR

===================  Toxicological Information	===================

Toxicological Information:ANIMAL DATA: INHALATION 0.5-HR LC50: 720,000
    PPM IN RATS. ORAL ALD: >2250 MG/KG IN RATS.  COMPOUND IS MILD SKIN
    AND EYE IRRITANT, UNTESTED FOR ANIMAL SENSITIZATION. TOXIC EFFECTS
    DESCRIBED IN ANIMAL E XPOSURES BY INHALATION OR INGESTION INCLUDE
    CNS EFFECTS, CARDIAC SENSITIZATION, RESPIRATORY AND LIVER EFFECTS.
    MICE EXPOSED FOR 23 MONTHS TO MIX OF CHLOROFLUORO CARBONS INCLUDING
    250,000 PPM OF "FREON " 114, DEMONSTRATED NO EVIDENCE OF
    CARCINOGENIC ACTIVITY. NO ANIMAL TEST REPORTS  DEFINE EMBRYOTOXIC,
    OR REPRODUCTIVE HAZARDS.TESTS IN BACTERIAL OR MAMMALIAN CELL
    CULTURES DEMONSTRATE NO MUTAGENIC ACT IVITY.

=====================  Ecological Information  =====================

Ecological:AQUATIC TOXICITY: 96-HOUR LC50, KILLIFISH:  45 PPM.

====================  Disposal Considerations  ====================

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE & LOCAL REGULATIONS.
    RECLAIM BY DISTILATION OR REMOVE TO A LICENSED WASTE DISPOSAL
    FACILITY.

===================  MSDS Transport Information  ===================

Transport Information:SHIPPING INFORMATION: DOT/ IMO/ IATA:  PROPER
    SHIPPING NAME: 1,2-DICHLORO-1,1,1,1-TETRAFLUOROETHANE, CLASS 2.2,
    UN1958, LABEL NONFLAMMABLE GAS. SHIPPING CONTAINERS: TANK CARS,
    TANK TRUCKS, CYLINDERS.

=====================  Regulatory Information  =====================

SARA Title III Information:DISCHLOSURE AS A TOXIC CHEMICAL IS REQUIRED
    UNDER SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
    REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372. TITLE III HAZARD
    CLASSIFICATIONS SECTIONS 31 1, 312: ACUTE: YES, CHRONIC: NO, FIRE:
    NO, REACTIVITY: NO.PRESSURE: NO. LISTS: EXTREMELY HAZARDOUS
    SUBSTANCE- NO.CRCLA HAZARDOUS SUBSTANCE - NO. TOXIC CHEMICALS -YES.
Federal Regulatory Information:TSCA INVENTORY STATUS:
    REPORTED/INCLUDED.

=======================  Other Information  =======================

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