VAN WATERS & ROGERS INC -- ORTHENE TURF, TREE & ORNAMENTAL SPRAY  -- 6840-00N064800
<pre>=====================  Product Identification  =====================

Product ID:ORTHENE TURF, TREE & ORNAMENTAL SPRAY
MSDS Date:01/01/1992
FSC:6840
NIIN:00N064800
=== Responsible Party ===
Company Name:VAN WATERS & ROGERS INC
Address:6100 CARILLON POINT
City:KIRKLAND
State:WA
ZIP:98033
Country:US
Info Phone Num:206-889-3400
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:DO735
=== Contractor Identification ===
Company Name:UNIVAR CORP, VAN WATERS AND ROGERS INC
Address:1363 S BONNIE BEACH PL
Box:City:LOS ANGELES
State:CA
ZIP:90054
Country:US
CAGE:08455
Company Name:VAN WATERS & ROGERS SUBSIDIARY OF UNIVAR
Address:6100 CARILLON POINT
City:KIRKLAND
State:WA
ZIP:98033
Country:US
Phone:425-889-3400
CAGE:DO735

=============  Composition/Information on Ingredients  =============

Ingred Name:PHOSPHORODITHIOIC ACID, N-ACETYL-, O,S-DIMETHYL ESTER;
    (ACEPHATE:O,S-DIMETHYL ACETYLPHOSPHORAMIDOTHIOATE)
CAS:30560-19-1
RTECS #:TB4760000
Fraction by Wt: 75%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:SILICA AMORPHOUS PRECIPITATED AND GEL; (SYNTHETIC AMORPHOUS
    SILICA (PRECIPITATED OR GEL))
CAS:112926-00-8
Fraction by Wt: 21.2%
OSHA PEL:N/K 
ACGIH TLV:10 MG/M3 (MFR)

Ingred Name:SUPDAT:ARREST MAY BE FATAL. INGEST:SLIGHTLY TOX TO INTERNAL
    ORGANS IF SWALLOWED. DEGREE OF INJURY WILL DEPEND (ING 4)
RTECS #:9999999ZZ

Ingred Name:ING 3:ON AMT ABSORBED FROM GUT. SIGNS & SYMPS MAY INCL, BUT
    MAY NOT BE LIMITED TO, HDCH, DIZZ, WEAK, CONSTRICTION(ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4:OF PUPIL OF EYE, BLURRED OR DARK VISION, EXCESS
    SALIVATION OR NASAL DISCHARGE, PROFUSE SWEAT, ABDOMINAL (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5:CRAMPS, NAUS & VOMIT. INCONTINENCE, UNCON & CONVLS
    INDICATE SEVERE POISONING. IN UNTREATED SEV POISONING (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:RESPIRATORY DEPRESSION OR CARDIAC ARREST MAY BE
    FATAL. CONTACT NEHC FOR TOXICOLOGICAL INFORMATION .
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC:CTR, OR EMERGENCY CENTER BEFORE INDUCING
    VOMITING. DO NOT INDUCE VOMITING OR GIVE ANYTHING BY (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:MOUTH TO AN UNCONSCIOUS PERSON. TAKE PERSON AND
    PRODUCT CONTAINER TO THE NEAREST EMERGENCY TREATMENT (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:CENTER. NOTE TO PHYSICIAN:THIS MATERIAL CONTAINS A
    CHOLINESTERASE INHIBITOR. MEASUREMENT OF BLOOD (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10:CHOLINESTERASE ACTIVITY MAY BE USEFUL IN MONITORING
    ANTIDOTAL. 2-PAM (PROTOPAM) IS ALSO ANTIDOTAL AND (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:MAY BE USED IN CONJUNCTION WITH ATROPINE BUT SHOULD
    NOT BE USED ALONE.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC:LITTER, CLAY RAGS OR OTHER ABSORBENT AND PLACE
    IN DISPOSABLE CONTAINER.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50:(ORAL,RAT) 1494 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:SLIGHTLY IRRITATING & COULD
    CAUSE PRLNGD IMPAIRMENT OF VISION. DEGREE OF INJURY WILL DEPEND ON
    AMT OF MATL THAT GETS IN EYE & SPEED AND THOROUGHNESS OF FIRST AID.
    SIGNS & SYMPS MAY INCLUDE P AIN, TEARS, SWELL, REDNESS & BLURRED
    VISION. SKIN:NOT EXPECTED TO CAUSE PRLNGD/SIGNIFICANT IRRIT. IF
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:ABSORBED THRU SKIN, SUBSTANCE IS
    CONSIDERED PRACTICALLY NON-TOXIC TO INTERNAL ORGANS. INHAL:TOX HAS
    NOT BEEN DETERM. HOWEVER, IT MAY BE SLIGHTLY TOX TO INTERNAL ORGANS
    IF INHALED. DEGREE OF I NJURY WILL DEPEND ON CONC & DURATION
    OFEXPOS. SIGNS & SYMPS INCL, BUT MAY NOT BE LIMITED TO, HDCH, DIZZ,
    WEAK, (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:EYE:FLUSH IMMED W/FRESH WATER FOR @ LST 15 MINS WHILE HOLDING
    EYELIDS OPEN. REMOVE CONT LENSES IF WORN. IF IRRIT PERSISTS, SEE
    MD. SKIN:WASH THOROUGHLY W/SOAP & WATER. REMOVE & WASH CONTAMD
    CLTHG. INH AL:MOVE PERSON TO FRESH AIR. SEE MD IF DISCOMFORT/IRRIT
    CONTINUES. INGEST:DRINK 1-2 GLASSES OF WATER (OR MILK) & INDUCE
    VOMIT BY TOUCHING BACK OF THROAT W/FINGER. IF POSS, CONT MD, POIS
    CTL (ING 8)

=====================  Fire Fighting Measures  =====================

Extinguishing Media:CO*2, DRY CHEMICAL, FOAM AND WATER FOG.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . PRODS OF
    COMBUST MAY BE TOXIC. AVOID BRTHG SMOKE & MISTS. MINIMIZE AMT OF
    WATER USED FOR FIRE FIGHTING. (SUPDAT)
Unusual Fire/Explosion Hazard:NORMAL COMBUSTION FORMS CARBON DIOXIDE,
    WATER VAPOR & MAY PRDCE OXIDES, SULFUR, NITROGEN & PHOSPHOROUS.
    INCOMPLETE COMBUSTION CAN PRDCE CARBON MONOXIDE.

==================  Accidental Release Measures  ==================

Spill Release Procedures:CLEAN UP SPILL IMMED, OBSERVING PREC IN PROT
    EQUIP SECTION. VACUUM W/MACHINES EQUIPPED W/HIGH EFFICIENCY
    FILTERS/SWEEP UP MATL & PLACE IN DISPOSABLE CNTNR. SCRUB CONTAMD
    AREA W/DETERGENT & WATER USING  STIFF BROOM. PICK UP, LIQ W/OIL,
    DRY, CAT(ING 13)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP PESTICIDE IN ORIGINAL CNTNR. DO
    NOT STORE/TRANSPORT NEAR FOOD/FEED. DO NOT CONTAMINATE FOOD/FEED.
    DO NOT PUT CONCENTRATE INTO FOOD/DRINK CNTNRS.
Other Precautions:DO NOT DILUTE CONCENTRATE IN FOOD/DRINK CNTNRS. STORE
    IN COOL, DRY PLACE, OUT OF DIRECT SUNLIGHT. KEEP CHILDREN & ANIMALS
    AWAY FROM TREATED AREAS UNTIL THESE AREAS HAVE DRIED. READ &
    OBSERVE ALL PRECA TUIONS ON PRODUCT LABEL.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WEAR NIOSH APPROVED RESPIRATORY PROTECTION WHEN
    WORKING W/THIS MATERIAL UNLESS VENTILATION IS ADEQUATE TO KEEP
    AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE STANDARDS.
Ventilation:USE ADEQUATE VENT TO KEEP AIRBORNE CONCS OF THIS MATL BELOW
    RECOMMENDED EXPOSURE STANDARD.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
    PROTECTIVE CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:CONTAIN & ISOLATE RUNOFF & DEBRIS FOR PROPER DISP. EFTS
    OF OVEREXP:CONSTRICTION OF PUPIL OF EYE, BLURRED/DARK VISION,
    EXCESS SALIVATION/NASAL DISCHARGE, PROFUSE SWEAT, ABDOM CRAMPS, NA
    US & VOMIT. INCONTINENCE, UNCON & CONVLS INDICATE SEV POISONING. IN
    UNTREATED SEV POISONING, RESP DEPRESS/CARD (ING 3)

==================  Physical/Chemical Properties  ==================

Solubility in Water:SOLUBLE
Appearance and Odor:WHITE POWDER WITH A STRONG CABBAGE-LIKE OR
    MERCAPTAN-TYPE ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH ALKALINE MATERIALS.
Stability Condition to Avoid:STABLE AT TEMPERATURES BELOW 180F (82C).
Hazardous Decomposition Products:CONTACT WITH ALKALINE MATERIALS
    INCLUDING HYPOCHLORITE OXIDANTS, MAY PRODUCE NOXIOUS GASES.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSAL SHOULD BE IN ACCORDANCE WITH FEDERAL,
    STATE, AND LOCAL REGULATIONS . CHECK GOVERNMENTAL REGULATIONS AND
    LOCAL AUTHORITIES FOR APPROVED DISPOSAL OF THIS MATERIAL.

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 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
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 particular situation.