Material Safety Data Sheet
Lead

ACC# 12510
Section 1 - Chemical Product and Company Identification

MSDS Name: Lead
Catalog Numbers: S71957, S719571, S75257, S80049, L18-500, L246-500, L27-1LB, L271RL, NC9657609, NC9888945, XXL24625KG
Synonyms: Lead metal.
Company Identification:
              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7439-92-1 Lead 99.8 231-100-4

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: bluish white, silvery gray solid.
Caution! Causes eye and skin irritation. May be absorbed through intact skin. May cause central nervous system depression. May cause kidney damage. May cause adverse reproductive effects. May cause fetal effects.
Target Organs: Kidneys, central nervous system, blood forming organs.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation. May be absorbed through the skin.
Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. Ingestion of lead compounds can cause toxic effects in the blood-forming organs, kidneys and central nervous system. Symptoms of lead poisoning or plumbism include weakness, weight loss, lassitude, insomnia, and hypotension. It also includes constipation, anorexia, abdominal discomfort and colic.
Inhalation: May cause respiratory tract irritation. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. May cause effects similar to those described for ingestion.
Chronic: Chronic exposure may cause reproductive disorders and teratogenic effects. Chronic exposure to lead may result in plumbism which is characterized by lead line in gum, headache, muscle weakness, mental changes.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure.
Ingestion: Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.
Antidote: The use of Dimercaprol or BAL (British Anti-Lewisite) as a chelating agent should be determined by qualified medical personnel. The use of d-Penicillamine as a chelating agent should be determined by qualified medical personnel. The use of Calcium disodium EDTA as a chelating agent should be determined by qualified medical personnel.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible. Dust can be an explosion hazard when exposed to heat or flame.
Extinguishing Media: For small fires, use water spray, dry chemical, carbon dioxide or chemical foam. Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Wash clothing before reuse.
Storage: Store in a cool, dry place. Keep from contact with oxidizing materials. Keep containers tightly closed.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Lead 0.05 mg/m3 TWA 0.050 mg/m3 TWA 100 mg/m3 IDLH 50 æg/m3 PEL (as Pb); 30 æg/m3 Action Level (as Pb. Poison - see 29 CFR 1910.10 25)

OSHA Vacated PELs: Lead: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: bluish white, silvery gray
Odor: none reported
pH: Not applicable.
Vapor Pressure: 1.3 mm Hg @ 970C
Vapor Density: Not available.
Evaporation Rate:Not applicable.
Viscosity: Not applicable.
Boiling Point: 1740 deg C
Freezing/Melting Point:327.4 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble in water.
Specific Gravity/Density:11.3
Molecular Formula:Pb
Molecular Weight:207.2

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Dust generation, excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Lead/lead oxides.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7439-92-1: OF7525000
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 7439-92-1:


Epidemiology: There are several reports that certain lead compounds administered to animals in high doses are carcinogenic, primarily producing renal tumors. Salts demonstrating carcinogenicity in animals are usually soluble salts. Epidemiological studies have not shown a relationship between lead exposure and the incidence of cancer in lead workers. However, one study of lead-exposed workers demonstrated a statistically significant elevation in the standardized mortality ratio for gastric and lung cancer in battery plant workers only.
Teratogenicity: Lead penetrates the placental barrier and has caused fetal abnormalities in animals. Excesssive exposure to lead during pregnancy has caused neurological disorders in infants.
Reproductive Effects: Reproductive effects from lead have been documented in animals and human beings of both sexes. In battery workmen with a mean exposure of 8.5 years to lead, there was an increased frequency of sperm abnormalities as compared with a control group.
Mutagenicity: Mutagenic effects have occurred in humans.
Neurotoxicity: Subtle neurologic effects have been demonstrated with relatively low blood levels of lead. The performance of lead workers on various neurophysiological tests was mildly reduced when compared with a control group. Anxiety, depression, poor concentration, forgetfulness, mild reductions in motor and sensory nerve conduction velociities have been documented in lead-exposed workers.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. LC50 Japanese quail (Coturnix japonica), males or females, 14 days old, oral (5-day adlibitum in diet) >5,000 ppm; at 1000, 2236 & 5000 onset of toxic signs began at 7, 7 & 7 days and remissed at 11, 11 & 12 days, respectively, no mortality was observed; control references were dieldrin & dicrotophos; corn oil diluent was added to diet at ratio of 2:98 by wt; (extreme concentrations: 1,000-5,000 ppm) /Lead metal, 100%.
Environmental: Terrestrial: Extremely stable metal. While some corrosion may be expected in soil, generally an inert coat of an insoluble salt will form and limit further corrosion. Aquatic: Lead will simply sink into the sediment. Atmospheric: Will be in particulate matter and be subject to washout and gravitational settling. Will biodegrade and bioconcentrate.
Physical: No information available.
Other: For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND EXPOSURE DATA."

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: Not regulated Not Regulated
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL
TSCA
     CAS# 7439-92-1 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 7439-92-1: 10 lb final RQ (no reporting of releases of this hazardous substance is required
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 7439-92-1: immediate, delayed.
Section 313
     This material contains Lead (CAS# 7439-92-1, 99.8%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     CAS# 7439-92-1 (listed as Lead compounds) is listed as a hazardous air      pollutant (HAP).
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.      CAS# 7439-92-1 is listed as a Priority Pollutant under the Clean      Water Act. CAS# 7439-92-1 is listed as a Toxic Pollutant under the Clean Water Act.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7439-92-1 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65
The following statement(s) is(are) made in order to comply with the California Safe Drinking Water Act:
WARNING: This product contains Lead, a chemical known to the state of California to cause cancer. WARNING: This product contains Lead, a chemical known to the state of California to cause male reproductive toxicity.
California No Significant Risk Level: CAS# 7439-92-1: 15 æg/day NSRL (oral)

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     T N
Risk Phrases:
     R 20/22 Harmful by inhalation and if swallowed.
     R 33 Danger of cumulative effects.
     R 61 May cause harm to the unborn child.
     R 62 Possible risk of impaired fertility.

Safety Phrases:

WGK (Water Danger/Protection)
     CAS# 7439-92-1: No information available.
Canada - DSL/NDSL
     CAS# 7439-92-1 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D2A.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 7439-92-1 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 4/29/1999
Revision #4 Date: 10/03/2005

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.