CAROLINA BIOLOGICAL SUPPLY CO -- 86-1490, ETHYL ACETATE -- -
===================== Product Identification ===================== Product ID:86-1490, ETHYL ACETATE MSDS Date:09/05/2000 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD City:BURLINGTON State:NC ZIP:27215-3387 Country:US Info Phone Num:800-227-1150 Emergency Phone Num:800-227-1150 Chemtrec Ind/Phone:(800)424-9300 CAGE:59896 === Contractor Identification === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD Box:City:BURLINGTON State:NC ZIP:27215-3387 Country:US Phone:800-227-1150/910-584-0381 Contract Num:MDA414-01-P-0084 CAGE:59896 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYL ACETATE CAS:141-78-6 RTECS #:AH5425000 = Wt:100. OSHA PEL:1400 MG/M3;400 PPM ACGIH TLV:1440 MG/M3;400 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, MOUSE): 4100 MG/KG (EST.) Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION. SKIN: MAY CAUSE IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL DISCOMFORT. INHALATION: MAY CAUSE IRRITATION TO RESPIRATORY TRACT. TARGET ORGANS: EYES, SKIN, RESPIRATORY PASSAGES AND MUCOUS SURFACES. Explanation of Carcinogenicity:NOT LISTED AS CAUSING CANCER BY IARC, NTP, OR OSHA. Effects of Overexposure:EYES AND SKIN: IRRITATION. INGESTION: GI DISCOMFORT. INHALATION: IRRITATION OF RESPIRATORY TRACT. Medical Cond Aggravated by Exposure:RESPIRATORY, KIDNEY, LIVER, SKIN, AND BLOOD DISORDERS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES, LIFTING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION. SKIN: WASH AREA FOR 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. GET MEDICAL ATTENTI ON IF NEEDED. INGESTION: IF CONSCIOUS, GIVE PLENTY OF WATER AND INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. CALL PHYSICIAN OR POISON CONTROL CENTER. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS P ERSON. INHALATION: MOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING DIFFICULT; GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=-4.4C, 24.F Autoignition Temp:=426.7C, 800.F Extinguishing Media:USE DRY CHEMICAL, CO2, OR APPROPRIATE FOAM. Fire Fighting Procedures:FIREFIFGTERS SHOULD WEAR FULL PROTECTIVE EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:A VERY DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. VAPOR CAN TRAVEL DISTANCES TO IGNITION SOURCE AND FLASH BACK. HOT ORGANIC VAPORS OR MISTS ARE SUSCEPTIBLE TO SUDDEN SPONTANEOUS COMBUSTION W HEN MIXED WITH AIR. IGNITION MAY OCCUR AT TEMPERATURES BELOW PUBLISHED AUTOIGNITION OR IGNITION TEMPERATURES. ================== Accidental Release Measures ================== Spill Release Procedures:VENTIATE AREA OF SPILL. ELIMINATE ALL SOURCES OF IGNITION. REMOVE ALL NON-ESSENTIAL PERSONNEL FROM AREA. CLEAN-UP PERSONNEL SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND CLOTHING. ABSORB MATERIAL WITH S UITABLE ABSORBENT AND CONTAINERIZE FOR DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN A COOL AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. RETAINED RESIDUE MAY MAKE EMPTY COLNTAINERS HAZ ARDOUS; USE CAUTION ! Other Precautions:WASH THROUGHLY AFTER HANDLING. SO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR SHOULD BE WORN IF PEL OR TLV IS EXCEEDED. Ventilation:LOCAL EXHAUST: PREFERRED. MECHANICAL (GENERAL): ACCEPTABLE. SPECIAL: NO. OTHER: NO. Protective Gloves:WEAR BUTYL OR EQUIVALENT PROTECTIVE GLOVES. Eye Protection:SPLASH PROOF CHEMICAL SAFETY GOGGLES SHOULD BE WORN AT ALL TIMES. Other Protective Equipment:LAB COAT, EYE WASH, AND SAFETY SHOWER. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE INTERNALLY. DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. Supplemental Safety and Health PRODUCT CODES: 86 -1490,86-1492, 86-1510, 86-1512. SIZE 500ML, 1 GAL, 4 L. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=77.2C, 171.F Melt/Freeze Pt:=83.6C, 182.5F Vapor Pres:100 MM HG @27.0 C Vapor Density:3.04(AIR=1 Spec Gravity:0.894@25C (H2O=1) Evaporation Rate & Reference:7.5 (H2O=1) Solubility in Water:1 ML IN 10 ML WATER@ 25C. Appearance and Odor:CLEAR, VOLATILE, FLAMMABLE LIQUID; CHARACTERISTIC FRUITY ODOR. Percent Volatiles by Volume:99 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES IGNITES ON CONTACT WITH POTASSIUM TERT-BUTOXIDE. VIOLENT REACTION WITH CHLORESULFONIC ACID. POTENTIALLY EXPLOSIVE REACTION WITH LITHIUM TETRAHYDROALUMINATE. INCOMPATIBILE WITH ACIDS, OXIDIZERS, STRONG ALKALIES, NITRATES. Stability Condition to Avoid:AVOID CONTACT WITH IGNITION SOURCE HEAT. Hazardous Decomposition Products:CARBON OXIDES (COX). Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:TOXICITY DATA: EFFECTS OF OVEREXPOSURE: ACUTE: SEE HEALTH HAZARDS. CHRONIC: MUTATION DATA CITED. NOT LISTED AS CAUSING CANCER BY IARC, NTP, OR OSHA. CONDITIONS AGGRAVATED BY OVER EXPOSURE: RESPIRATOR Y, KIDNEY, LIVER, SKIN, AND BLOOD DISORDERS. TARGET ORGANS: EYES, SKIN, RESPIRATORY PASSAGES, AND MUCOUS SURFACES. PRIMAYRY ROUTES OF ENTRY: INGESTION, INHALATION. ===================== Ecological Information ===================== Ecological:EPA WASTE NUMBERS: U112 DOO1.THE PRODUCTS OF DEGRADATION ARE NORE TOXIC. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE. =================== MSDS Transport Information =================== Transport Information:DESCRIPTION: ETHYL ACETATE, 3, UN 1173, I I. ===================== Regulatory Information ===================== SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311 / 312 REPORTING: ACUTE, CHRONIC FIRE. PRODUCT OR COMPONENTS 261.33: ETHYL ACETATE; SARA EHS, SECTION 302, TPQ: NO; SARA SEC. 313 CHEMICALS: NAME LIST: NO CHEMICAL CATEGORY: NO; CERCLA SEC. 103, RQ LBS: 5000 LBS; RCRA SEC.: YES. Federal Regulatory Information:EPA TSCA STATUS: ON TSCA INVENTORY. State Regulatory Information:ETHYL ACETATE IS LISTED BY THE STATE OF MASSACHUSETTS AND THE STATE OF PENNSYLVANIA. WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER. WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.