FISHER SCIENTIFIC -- M-7, MAGNESIUM -- 6810-00N015846
===================== Product Identification ===================== Product ID:M-7, MAGNESIUM MSDS Date:04/11/1986 FSC:6810 NIIN:00N015846 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIR LAWN State:NJ ZIP:07410-2802 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ING 2:VIOLENTLY UNLESS MOISTURE IS PRESENT. MAY IGNITE IF EXPOSED TO AIR/MOISTURE. SOLID FORM WILL MELT AS IT (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:BURNS TO FORM PUDDLES OF MOLTEN MAGNESIUM, WHICH PRESENT AN EXPLOS HAZ IN PRESENCE OF WATER. MAY REIGNITE (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4:AFTER FIRE IS OUT. RTECS #:9999999ZZ Ingred Name:CONDTNS (STAB):REACTIONS. AVOID:MOIST AIR, STREAM, MOISTURE. RTECS #:9999999ZZ Ingred Name:MATL TO AVOID:SILICON DIOXIDE AND OTHERS. FOR COMPLETE LISTING OF MATERIALS TO AVOID CONTACT NEHC . RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXPOS:EYES:METAL IN ANTERIOR CHAMBER OF EYES HAS RESULTED IN FORMATION OF HYDROGEN BUBBLES, BUT (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:NO APPARENT INJURY. INTRAOCULAR PRESS REMAINED SUBNORMAL FOR SEV WEEKS WHILE METAL WAS BEING ABSORBED. (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:INGEST:CONT W/TISSUE WILL CAUSE IRRIT W/BURNS OF GI TRACT. CHRONIC:FINE DUST HAS CAUSED COMPLAINTS OF (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:IRRIT & COUGH W/COLORED SPUTUM. RTECS #:9999999ZZ Ingred Name:SPILL PROC:DRY CONTR & COVER; MOVE CONTR FROM SPILL AREA. FOR SMALL LIQ SPILLS, TAKE UP W/SAND/OTHER ABSORB (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:MATL & PLACE INTO CONTR FOR LATER DISP. FOR LARGER SPILLS, DIKE SPILL FOR LATER DISP. COVER POWDER SPILLS(ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:W/PLASTIC SHEET/TARP TO MIN SPREADING. KEEP UNNEC PEOPLE AWAY. ISOLATE HAZ AREA & DENY ENTRY. RTECS #:9999999ZZ Ingred Name:OTHER PREC:COLLECTOR UNITS WHERE MAGNESIUM MAY BE PRESENT. RTECS #:9999999ZZ Ingred Name:MAGNESIUM CAS:7439-95-4 RTECS #:OM2100000 Fraction by Wt: 100% Ingred Name:SUPDAT:(DUST, FLAKES, POWDER) IT MAY BE IGNITED BY SPARK/FLAME OF A MATCH. MAGNESIUM FIRES DO NOT FLARE UP (ING 3) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:DUST MAY CAUSE MUCOUS MEMBRANE IRRIT. FUMES MAY IRRIT RESP SYS & CAUSE METAL FUME FEVER W/COUGH, HDCH, FEVER, CHILLS, SNEEZING, NAUS, VOMIT, DYSPNEA, CHEST PAIN, & LEUKOCYTOSIS. SKIN:PARTI CLES WHICH PERFORATE SKIN & GAIN ENTRY THROUGH CUTS & SCRATCHES MAY PRODUCE SEV LOC LESION CHARACT BY (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:EVOLUTION OF GAS & AN INFLAMM REACTION, FREQUENTLY W/NARCOSIS, A CONDITION CALLED "CHEM GAS GANGRENE". GASEOUS BLEBS MAY DEV WITHIN 24 HRS OF INJURY W/EXTENSIVE NECROSIS, UNCERATIONS, SUBCUTA NEOUS EMPHYSEMA, & LYMPHANGITIS. LESIONIS VERY SLOW TO HEAL. HANDLING OF SUBSTANCE MAY ALSO CAUSE BURNS. (ING 8) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHAL:MOVE TO FRESH AIR IMMED. IF BRTHG HAS STOPPED, GIVE ARTIF RESP. KEEP AFFECTED PERSON WARM & AT REST. GET MD ATTN. SKIN:GET MD ATTN IMMED. EYE:WASH IMMED W/LRG AMTS OF WATER, OCCAS LIFTING LIDS, UNTIL NO EVIDENCE OF METAL REMAINS (APPROX 10-20 MIN). GET MD ATTN IMMED. INGEST:IF CONSCIOUS, GIVE LRG QUANTITIES OF WATER IMMED TO DILUTE. DO NOT INDUCE VOMIT, GET MD ATTN IMMED. ===================== Fire Fighting Measures ===================== Flash Point:COMBUSTIBLE Extinguishing Media:DRY GRAPHITE, SODA ASH, POWDERED SODIUM CHLORIDE/ OTHER SUITABLE DRY POWDER. DO NOT USE FOAM, CARBON (SUPDAT) Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . MOVE CONTR FROM FIRE AREA IF POSS. COOL CONTR EXPOS TO FLAME W/ WATER FROM SIDE. FOR MASSIVE FIRE IN(SUPDAT Unusual Fire/Explosion Hazard:MAGNESIUM IS DFCLT TO IGNITE BECAUSE HEAT IS CONDUCTED RAPIDLY AWAY FROM SOURCE OF IGNIT; IT MUST BE HEATED ABOVE ITS MELTING PT BEFORE IT WILL BURN. (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:RUNOFF TO SEWER MAY CREATE FIRE/EXPLOS HAZ. SHUT OFF IGNIT SOURCES. DO NOT TOUCH SPILLED MATL. STOP LEAK IF POSS WITHOUT RISK. DO NOT GET WATER ON SPILLED MATL/INSIDE CONTR. FOR SMALL DRY SPILLS, W/CL EAN SHOVEL PLACE MATL INTO CLEAN, (ING 12) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROHIBIT OPEN FLAMES, ELECT/GAS CUTTING, WELDING EQUIP WHERE MAGNESIUM DUST IS PRODUCED/HANDLED WHILE DUST-PRODUCING EQUIP IS IN OPERATION. Other Precautions:CONSULT NFPA PUB 48 & 651. SPECIAL PRECAUTIONS ARE NEEDED TO PREVENT IGNIT WHILE DRESSING WHEELS USED FOR GRINDING MAGNESIUM CASTINGS. NONSPARKING TOOLS SHOULD BE USED WHEN MAKING REPAIRS/ADJUSTMENTS AROUND GRINDING WHEELS, HOODS OR(ING 15) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:HIGH LEVELS:NIOSH/MSHA APPROVED SUPPLIED AIR RESPIRATOR WITH A FULL FACEPIECE, HELMET OR HOOD OR NIOSH/MSHA APPROVED SCBA WITH A FULL FACEPIECE. Ventilation:PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION SYSTEM. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:CHEM WORK GOGG & FULL LNGTH FCSHLD Other Protective Equipment:EYE-WASH FOUNTAIN WITHIN THE IMMED WORK AREA FOR EMERG USE. IMPERVIOUS CLTHG & EQUIP TO PREVENT RPTD/PRLNGD SKIN CONT. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EXTING MEDIA:TETRACHLORIDE/CO2. APPLICATION OF WATER SHOULD BE CONDUCTED W/CARE TO PREVENT CONT W/BURNING/MOLTEN MAGNESIUM. AVOID DIRECT VIEWING OF MAGNESIUM FIRES. FIRE FIGHT PROC:CARGO AREA, USE UNM ANNED HOSE HOLDER/MONITOR NOZZ; ELSE WITHDRAW & LET FIRE BURN. EXPLOS HAZ:HOWEVER, IN FINELY DIVIDED FORM (ING 2) ================== Physical/Chemical Properties ================== HCC:R2 Boiling Pt:B.P. Text:2025F,1107C Melt/Freeze Pt:M.P/F.P Text:1200F,649C Vapor Pres:1 @ 621C Spec Gravity:1.7 Solubility in Water:INSOLUBLE Appearance and Odor:ODORLESS, SILVER-WHITE METAL. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE W/ACIDS, AQUEOUS SOLUTIONS OF AMMONIUM SALTS, OILS, ALUMINUM, ETHYLENE OXIDE, HALOGENS, METHANOL, (ING 7) Stability Condition to Avoid:REACTS W/MOISTURE, ACID, ETC TO EVOLVE FLAMM HYDROGEN GAS. OXIDIZES IN MOIST AIR. HEAT MAY INTENSIFY SOME (ING 6) Hazardous Decomposition Products:DECOMPOSES ON CONTACT WITH WATER TO FORM CORROSIVE LITHIUM HYDROXIDE AND FLAMMABLE HYDROGEN GAS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.