BOSTIK INC -- CHEM CALK 900 WHITE 24/10.3, A12612 -- 8030-00N083545
===================== Product Identification ===================== Product ID:CHEM CALK 900 WHITE 24/10.3, A12612 MSDS Date:06/11/1996 FSC:8030 NIIN:00N083545 === Responsible Party === Company Name:BOSTIK INC Address:BOSTON ST City:MIDDLETON State:MA ZIP:01949 Country:US Info Phone Num:508-777-0100 Emergency Phone Num:800-227-0332 Preparer's Name:R.G. SONTAG CAGE:EO689 === Contractor Identification === Company Name:BOSTIK INC Address:BOSTON ST City:MIDDLETON State:MA ZIP:01949 Country:US Phone:508-777-0100 OR FAX 508-750-7212 CAGE:EO689 Company Name:BOSTIK INC. Address:211 BOSTON ST Box:City:MIDDLETON State:MA ZIP:01949 Country:US Phone:978-777-0100/800-227-0332 CAGE:5W425 ============= Composition/Information on Ingredients ============= Ingred Name:ISOCYANIC ACID, METHYLENE (3,5,5-TRIMETHYL-3,1-CYCLOHEXYLENE) ESTER; (ISOPHORONE DIISOCYANATE) (SARA 302) CAS:4098-71-9 RTECS #:NQ9370000 Fraction by Wt: 0.1% OSHA PEL:N/K ACGIH TLV:0.005 PPM Ingred Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (4,4'-DIPHENYLMETHANE DIISOCYANAGE (CALCULATED) (SARA 313) CAS:101-68-8 RTECS #:NQ9350000 Fraction by Wt: 1.1% OSHA PEL:0.02 PPM, C ACGIH TLV:0.005 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 6% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:CALCIUM CARBONATE CAS:1317-65-3 RTECS #:EV9580000 Fraction by Wt: 5.5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (LIGHT AROMTIC SOLVENT NAPHTHA) CAS:64742-95-6 RTECS #:WF3400000 Fraction by Wt: 0.9% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:XYLENE (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 4.1% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 150 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE, ETHYL-; (ETHYL BENZENE) (SARA 313) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 0.9% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 125 STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:PHTHALIC ACID, BIS(2-ETHYLHEXYL) ESTER; (DI(2-ETHYLHEXYL) PHTHALATE) CAS:117-81-7 RTECS #:TI0350000 Fraction by Wt: <0.1% OSHA PEL:100 PPM ACGIH TLV:100 PPM; 125 STEL EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (QUARTZ) CAS:14808-60-7 RTECS #:VV7330000 Fraction by Wt: <0.1% OSHA PEL:N/K ACGIH TLV:0.1 MG/M3 RDUST Ingred Name:ETHYLENE, CHLORO-; (VINYL CHLORIDE) (SARA 313) (CERCLA) CAS:75-01-4 RTECS #:KU9625000 Fraction by Wt: <0.1% OSHA PEL:N/K ACGIH TLV:5 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:SUPDAT:VINYL CHLORIDE ARE KNOWN TO STATE OF CA TO CAUSE CANCER. TARGET ORGANS:BLOOD, CNS, EYES, GI TRACT, SKIN, (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: KIDNEYS, LIVER, RESP SYS, LUNG. NOTE:IN TESTS ON ALBINO RATS, MDI AEROSOL PARTICLES SM ENOUGH TO INHALE (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:ARE RATED HIGHLY TOX ACCDG TO OSHA. HOWEVER, POLYURETHANE DIVISION OF SOCIETY OF PLACTICS INDUS, INC HAS (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:PETITIONED DOT TO DECLASSIFY MDI WHICH HAS BEEN RATED DOT POISON. SPI'S PETITION STATES: "...EVEN IN LAB (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: SETTING, IT IS VERY DFCLT TO CREATE RESPIRABLE AEROSOL ATM OF MDI CAPABLE OF CAUSING BIOLOGICAL HARM (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:BECAUSE OF MDI'S VERY LOW VP & HIGH VISCOSITY WHEN IN LIQ FORM." BOSTIK HAS DONE TESTS THAT SIMULATE USE (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: OF SEALANT & ADHESIVE PRODS. WHEN TRADITIONAL APPLICATN METHS USED, CHANCE OF AEROSOL FORM IS ESSNTLY (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17:NONEXISTANT. IN TESTS ON SEALANT, ACGIH TLV OF 5 PARTS/BILLION FOR MDI WAS NOT EXCEEDED EVEN IN AIR IMMED(ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: ADJACENT TO MULTIPLE EXTRUDED BEADS OF SEALANT. WHERE LG AREAS OF SEALANT/ADHESIVE TYPE PRODS APPLIED, (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19: BOSTIK RECOMS ADEQ VENT BE USED TO BE SURE ACGIH TLV OF MDI/OTHER HAZ CONSTITUENT IS NOT EXCEEDED IN WORK AREA. RTECS #:9999999ZZ Ingred Name:WASTE DISP: TOX CHARACTS THAT EXCEED MAX ALLOWABLE CONCS & IS THEREFORE HAZ WASTE: VINYL CHLORIDE-D043. IF PROD (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: ALTERED, PARTICULARLY TO POINT WHERE FILTERABLE SOLIDS PRESENT AT >0.5% LEVEL, CLASSIFICATION IS COMPLEX(ING 23) RTECS #:9999999ZZ Ingred Name:ING 22: & DEPENDS ON LEVEL OF CONTAMINANTS IN LIQ COMBINED W/EXTRACT OF SOLID. HAZ WASTE REMOVAL CONTRACTOR CAN ASSIST. RTECS #:9999999ZZ Ingred Name:PROT GLOVES: IMPERVIOUS PLASTIC GLOVES. RTECS #:9999999ZZ Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD . RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INFO SHOWN BELOW REFERS GENERALLY TO COMPONENT OF PROD BUT AS REQD BY OSHA 1910.1200 HAZS OF ANY INGRED MUST BE EXTENDED TO PROD AS WHOLE UNLESS TEST OF PROD PERFORMED. ANSI Z129.1-1982 USED AS GUIDE WHEN MSDS WRITTEN. INGEST/ABSORPTION: NO HAZ KNOWN AT THIS TIME. INHAL: HAZ IF INHALED. CNTCT: INGRED (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: CAUSES EYE &/OR SKIN IRRIT. INGRED CAUSES POSS IRREVERSIBLE EYE BURNS. SYMPS OF OVEREXP:IRRIT, SORE THROAT, DIZZ, GIDD, LT HEAD, DROW, LETHARGY, BRTHG DFCLTY, BREATHLESSNESS, CHEST PAIN, COU GH, SENSITIZER, NAUS, ABDOM PAIN, CRAMPS. CHRONIC: LONG TERM OVEREXP TO HAZ MATLS IN PROD ASSOC W/ASTHMA, (SUPDAT) Medical Cond Aggravated by Exposure:BRONCHIAL HYPERACTIVITY, ASTHMA. ======================= First Aid Measures ======================= First Aid:INGEST: CALL MD IMMEDIATELY . SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . INHAL: IF INHALED REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH TO MOU TH. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. EYES: IMMEDIATELY FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL MD. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:160F,71C Lower Limits:1.05% Upper Limits:6.79% Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . FOAMS WITH WATER. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:SWEEP UP MATERIAL USING SWEEPING COMPOUND AND PACKAGE THE SOLID PRODUCT IN STEEL DRUMS WHICH ARE IN GOOD CONDITION. THOROUGHLY CLEAN AREA WHERE SPILL OCCURRED. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL LOCATION (60-80F) AWAY FROM SUNLIGHT AND ANY SOURCE OF HEAT, SPARKS OR FLAME. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT BEING USED. Other Precautions:USE WITH ADEQUATE VENTILATION. AVOID PROLONGED OR REPEATED BREATHING OF VAPORS. AVOID SKIN CONTACT. USE IN AN AREA FREE FROM FLAME AND SPARKS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST IS PREFERRED TO KEEP VAPORS/PARTICULATES BELOW TLV VALUE. MECHANICAL AREAWIDE VENTILATION IS ACCEPTABLE. Protective Gloves:NEOPRENE RUBBER, NITRILE, (ING 24) Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 25) Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health HAZ DECOMP PRODS: CARBON MONOXIDE, WATER VAP. OXIDES OF NITROGEN OR WIDE VARIETY OF INNOCUOUS OR TOX FUMES. ALDEHYDES, HYDROGEN CHLORIDE, SULFUR DIOXIDE, TRACES OF HYDROGEN CYANIDE MAY ALSO BE PRDCED. EFTS OF OVEREXP: LUNG IMPAIRMENT, KIDNEY & LIVER DMG, POSS RESP SENSIT. DI(2-ETHYLHEXYL) PHTHALATE, QUARTZ, (ING 11) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>277F,>136C Vapor Pres:9 Vapor Density:3.77 Spec Gravity:1.22 Solubility in Water:0.0% Appearance and Odor:A PASTE IN VARIOUS COLORS WITH A SOLVENT ODOR. Percent Volatiles by Volume:8.7 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, STRONG ALKALIS, ALKALIS, STRONG ACIDS, ACIDS, ALCOHOLS, DETERGENTS, WATER. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:UNKNOWN DUE TO COMPLEX NATURE OF MATL. FUMES FROM COMPLETE/INCOMPLETE COMBUST OF MATL MAY INCL CARBON DIOXIDE, (SUPDAT) Conditions to Avoid Polymerization:CAN OCCUR WITH MOISTURE AND OTHER ISOCYANATE REACTANTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP I/A/W FED, STATE & LOC RULES. BE AWARE THAT STATE & LOC REQS MAY DIFFER WIDELY DEPENDING ON LOCATION & MAY DIFFER FROM FED RULES. THIS PROD, IF UNALTERED/MIXED W/ANY OTHER MATLS, CNTNS FOLLOWING CONTAMINANT LISTED IN 40CFR PART 261.24, (ING 21) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.