NATIONAL WELDERS SUPPLY CO INC -- ACETYLENE -- 6830-00-264-6752
===================== Product Identification ===================== Product ID:ACETYLENE MSDS Date:07/01/1994 FSC:6830 NIIN:00-264-6752 === Responsible Party === Company Name:NATIONAL WELDERS SUPPLY CO INC Address:810 GESCO Box:31007 City:CHARLOTTE State:NC ZIP:28231 Country:US Info Phone Num:704-333-5475(X308)/FAX 344-1711 Emergency Phone Num:800-866-4422/800-424-9300(CHEMTREC) CAGE:18264 === Contractor Identification === Company Name:NATIONAL WELDERS SUPPLY CO INC Address:810 GESCO ST Box:31007 City:CHARLOTTE State:NC ZIP:28231 Country:US Phone:704-333-5475 CAGE:18264 Company Name:NATIONAL WELDERS SUPPLY CO, INC Address:2330 BOWDENS FERRY ROAD Box:City:NORFOLK State:VA ZIP:23508 Country:US Phone:804-627-5673 CAGE:0SSR7 ============= Composition/Information on Ingredients ============= Ingred Name:ACETYLENE CAS:74-86-2 RTECS #:AO9600000 Fraction by Wt: >=98% Other REC Limits:NONE RECOMMENDED ACGIH TLV:ASPHYXIANT; 9596 ===================== Hazards Identification ===================== LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:AS A NARCOTIC GAS OR INTOXICANT, ACETYLENT CAUSES HYPERCAPNIA (AN EXCESSIVE AMOUNT OF CARBON DIOXIDE IN THE BLOOD). REPEATED EXPOSURES TO TOLERABLE LEVELS HAS NOT SHOWN DELETERIOUS EFFECTS. THE MAJOR PROPERTY IS THE EXCLUSION OF AN ADEQUATE SUPPLY OF OXYGEN TO THE LUNGS. Explanation of Carcinogenicity:ACETYLENE IS NOT LISTED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY NTP, IARC, OR OSHA. Effects of Overexposure:INHALATION:LOW CONCENTRATIONS (10-20% IN AIR) CAUSE SYMPTOMS SIMILAR TO THAT OF BEING INTOXICATED. HIGHER CONCENTRATIONS SO AS TO EXCLUDE AN ADEQUATE SUPPLY OF OXYGEN TO THE LUNGS CAUSING UNCONSCIOUSN ESS. Medical Cond Aggravated by Exposure:PERSONS IN ILL HEALTH WHERE SUCH ILLNESS WOULD BE AGGRAVATED BY EXPOSURE TO ACETYLENE SHOULD NOT BE ALLOWED TO WORK WITH OR HANDLE THIS PRODUCT. ======================= First Aid Measures ======================= First Aid:PROMPT MEDICAL ATTENTION IS MANDANTORY IN ALL CASES OF OVEREXPOSURE TO ACETYLENE. RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED BREATHING APPARATUS AND BE COGNIZANT OF EXTREME FIRE AND EXPLO SION HAZARD. ===================== Fire Fighting Measures ===================== Flash Point:GAS Autoignition Temp:Autoignition Temp Text:565F Lower Limits:2.2 Upper Limits:80 - 85 Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:IF POSSIBLE, STOP FLOW OF ESCAPING GAS. USE WATER SPRAY TO COOL SURROUNDING CONTAINERS. KEEP PERSONNEL FROM AREA SINCE HEATED CYLINDERS MAY RUPTURE VIOLENTLY. Unusual Fire/Explosion Hazard:GASEOUS ACETYLENE IS SPONTANEOUSLY COMBUSTIBLE IN AIR AT >30 PSIA. IT HAS A VERY LOW IGNITION ENERGY, FIRES CAN REIGNITE VIOLENTLY. DOES NOT DISSIPATE READILY. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE APPROPRIATE PROTECTIVE EQUIPMENT. IF LEAK IS IN USER'S EQUIPMENT, BE CERTAIN TO PURGE PIPING WITH AN INERT GAS PRIOR TO ATTEMPTING REPAIRS. IF LEAK IS IN CONTAINER OR VALVE, CONTACT SUPPLIER IMMEDIATELY. Neutralizing Agent:MFR GAVE NO INFORMATION ON MSDS. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT FROM PHYSICAL DAMAGE. STORE UPRIGHT & SECURED IN COOL,DRY,WELL-VENTILATED AREA APPROPRIATE FOR FLAMMABLE GASES. KEEP TEMPERATURE <125F/52C. Other Precautions:DANGER! HANDLE ONLY PER COMPRESSED GAS ASSN. PROCEDURES. SEE CGA PAMPHLETS G-1, P-1, P-14 & SAFETY BULLETIN SB-2. GROUND & BOND ALL LINES & EQUIPMENT. DO NOT REFILL CYLINDERS. DO NOT ROLL, SLIDE OR DR AG CYLINDERS, USE A CYLINDER TRUCK. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:POSITIVE PRESSURE AIR LINE OR SELF-CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE FOR EMERGENCY USE. Ventilation:HOOD W/FORCED VENTILATION. MECHANICAL EXHAUST I/A/W ELECTRICAL CODES. LOCAL EXHAUST TO PREVENT ACCUMULATIONS >LEL. Protective Gloves:PVC OR RUBBER Eye Protection:SAFETY GOGGLES OR GLASSES. Other Protective Equipment:SAFETY SHOES, SAFETY SHOWER. Work Hygienic Practices:MFR:? HMIS:USE GOOD INDUSTRIAL HYGIENE PRACTICES. MINIMIZE CONTACT & WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health SEGREGATE FULL & EMPTY CYLINDERS. ELIMINATE ALL IGNITION SOURCES FROM STORAGE & USE AREAS. USE ONLY NON-SPARKING OR EXPLOSION PROOF ELECTRICAL EQUIPMENT. ================== Physical/Chemical Properties ================== HCC:G2 NRC/State Lic Num:NONE Boiling Pt:B.P. Text:-119F,-84C Melt/Freeze Pt:M.P/F.P Text:-113F,-81C Vapor Pres:4450 KPA Vapor Density:1.107KG/M3 Spec Gravity:0.906 Evaporation Rate & Reference:N/A, DISSOLVED GAS Solubility in Water:SOLUBLE Appearance and Odor:A COLORLESS GAS W/AN ETHEREAL ODOR (COMMERCIAL ACETYLENE HAS A GARLIC ODOR) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:NO OXYGEN AND OTHER OXIDIZERS INCLUDING ALL OF THE HALOGENS AND HALOGEN COMPOUNDS, COPPER, MERCURY, SILVER, BRASS. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES. DO NOT ALLOW THE FREE GAS TO EXCEED 30 PSIA. AVOID SUDDEN SHOCK OR HEAT. Hazardous Decomposition Products:CARBON AND HYDROGEN. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF WASTE OR UNUSED QUANTITIES. RETURN IN THE SHIPPING CONTAINER PROPERLY LABELED, WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE PROTECTION CAP IN PLACE TO YOUR SUPPLI ER. FOR EMERGENCIES, CONTACT SUPPLIER. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.